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Formation of toxic gases during pyrolysis of polyacrylonitrile and nylons

✍ Scribed by M. Nielsen; P. Jurasek; J. Hayashi; E. Furimsky


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
529 KB
Volume
35
Category
Article
ISSN
0165-2370

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## Abstract The rate of HCN evolution during the inert pyrolysis of pyridine in the temperature range of 900–1000Β°C was determined in a flow system using a stirred‐flow reactor. The data indicated that HCN was formed through a sequence of reactions rather than during the initial step(s) involving t

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This short note describes studies of the pyrolysis of methacrylonitrile over a wide range of temperatures under flowing nitrogen at atmospheric pressure. Hydrogen cyanide was not found to be a primary product, but several organic nitriles are formed which decompose at higher temperature ( > 1100 K)