Self-Assembly of an Alkali Metal Cluster
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Snehadrinarayan Khatua; Sohaham Dasgupta; Kumar Biradha; Manish Bhattacharjee
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Article
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2005
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John Wiley and Sons
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English
⚖ 209 KB
👁 1 views
## Abstract A new tridentate ligand, {(3,5‐di‐__tert__‐butyl‐2‐hydroxybenzyl)amino}acetic acid, has been synthesized. This ligand forms [{Na~4~(H~2~O)~4~(μ‐H~2~O)~2~}(Mo~2~O~5~L~2~)~2~] (1), which contains an Na~4~^4+^ cluster cation stabilized by [LMoO~2~(μ‐O)MoO~2~L]^2–^, upon reaction with Na~2~