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Formation of TiO2(B) by proton exchange and thermolysis of several alkali metal titanate structures

✍ Scribed by T.P. Feist; S.J. Mocarski; P.K. Davies; A.J. Jacobson; J.T. Lewandowski


Book ID
104201034
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
766 KB
Volume
28-30
Category
Article
ISSN
0167-2738

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## Abstract A new tridentate ligand, {(3,5‐di‐__tert__‐butyl‐2‐hydroxybenzyl)amino}acetic acid, has been synthesized. This ligand forms [{Na~4~(H~2~O)~4~(μ‐H~2~O)~2~}(Mo~2~O~5~L~2~)~2~] (1), which contains an Na~4~^4+^ cluster cation stabilized by [LMoO~2~(μ‐O)MoO~2~L]^2–^, upon reaction with Na~2~