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Formation of Three C 4 H 3 N Isomers from the Reaction of CN (X 2 Σ + ) with Allene, H 2 CCCH 2 (X 1 A 1 ), and Methylacetylene, CH 3 CCH (X 1 A 1 ): A Combined Crossed Beam and Ab Initio Study

✍ Scribed by Balucani, N.; Asvany, O.; Kaiser, R.-I.; Osamura, Y.


Book ID
126436147
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
346 KB
Volume
106
Category
Article
ISSN
1089-5639

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✍ N. Balucani; O. Asvany; Y. T. Lee; R. I. Kaiser; N. Galland; M. T. Rayez; Y. Han 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 186 KB

## Abstract A novel supersonic beam of ground‐state boron atoms [B(^2^P)] was employed to investigate the reaction of B(^2^P) with acetylene [C~2~H~2~(^1^Σ~g~^+^)] at an average collision energy of 16.3±0.4 kJ mol^−1^ at the most fundamental microscopic level. The crossed molecular beam technique w