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Formation of Thioamide Derivatives from Reactions of Isothiocyanates with Oxazol-2-amines

โœ Scribed by Crank, G; Khan, HR


Book ID
111873479
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1985
Tongue
English
Weight
562 KB
Volume
38
Category
Article
ISSN
0004-9425

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Unexpected formation of novel pyrrole de
โœ Hirofumi Nakano; Tomoaki Ishibashi; Toshihiko Sawada ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 143 KB

The reaction of thioamides with DMAD gave the pyrrole derivatives in good yield and the thiophene derivatives as a byproduct. These were formed by 1,3-dipolar cycloaddition of themodynamicaly stable azomethine ylide or less stable thiocarbonyl ylide with DMAD, followed by elimination of thioaldehyde