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Formation of the silylene-bridged complex Fe2(CO)6(μ2-SiCl2)3fromcis-Fe(CO)4(SiCl3)2: an experimental and computational study

✍ Scribed by Van An Du; Gregor N. Stipicic; Maria Bendova; Ulrich Schubert


Book ID
106214404
Publisher
Springer Vienna
Year
2010
Tongue
English
Weight
359 KB
Volume
141
Category
Article
ISSN
0026-9247

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✍ W. Petz; F. Weller; A. Barthel; C. Mealli; J. Reinhold 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 253 KB 👁 1 views

The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3±n (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri