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Formation of the quaternary compounds Nd3(T1−xSix)33B10 (T=Co, Ni; 0.115≤x≤0.150)

✍ Scribed by Heng Zhang; S.J. Campbell; Hong-Shuo Li; E. Wu

Book ID
117625001
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
598 KB
Volume
284
Category
Article
ISSN
0925-8388

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✍ Shiro Hikichi; Michito Yoshizawa; Yasuyuki Sasakura; Hidehito Komatsuzaki; Yoshi 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 531 KB

The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.