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Formation of the platinum-olefin bond catalyzed by SnCl3-

✍ Scribed by Pietropaolo, Rosario; Dolcetti, Giuliano; Giustiniani, Mario; Belluco, Umberto

Book ID
126159990
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
408 KB
Volume
9
Category
Article
ISSN
0020-1669

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The reaction of ortho-alkynylphenylureas 1 having a carbamoyl group attached to the nitrogen atom proceeded in the presence of catalytic amounts of PtI 4 , affording corresponding indole-3-carbamides 2 in moderate to high yields. In addition, the platinum-catalyzed cyclization of ortho-alkynylphenyl