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Formation of the bis(1,1′-bicyclo[1.1.1]pentane) system in the radical reactions of [1.1.1]-propellane

✍ Scribed by N. S. Zefirov; N. K. Sadovaya; L. S. Surmina; I. A. Godunov; A. S. Koz'min; K. A. Potekhin; A. V. Maleev; Yu. T. Struchkov


Book ID
112448319
Publisher
Springer
Year
1988
Tongue
English
Weight
64 KB
Volume
37
Category
Article
ISSN
1573-9171

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The electronic structure of bicyclo [1.1
✍ J.M. Lehn; G. Wipff 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 444 KB

Ab initio SCF cafwhtions have been performed on bicycle [ 1.1.1 f pentsne aird on its bridgehead anion and cation. The most striking result ties in the strong interaction between the two bridgehead sites which may be related to the properties of thi!; strained molecuie.