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Formation of S,S-diphenyl-S-methoxythiazyne Ph2S(OMe)(≡N) in the alkaline hydrolysis of S,S-diphenyl-N-halosulfilimines

✍ Scribed by Toshiaki Yoshimura; Eiichi Tsukurimichi; Hiroshi Kita; Hiroshi Fujii; Choichiro Shimasaki

Book ID
104244970
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
111 KB
Volume
30
Category
Article
ISSN
0040-4039

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The structures of diphenyl(diphenylsulfi
The structures of diphenyl(diphenylsulfimido)(nitrido)sulfur(VI) and diphenyl(diphenyl-sulfodiimido)(nitrido)sulfur(VI), Ph2(X)S=N–(Ph2)S≡N (X = lone pair, NH)
✍ Takayoshi Fujii; Teruyoshi Fujimori; Shin Miyoshi; Satoru Murotani; Masanori Ohk 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB

## Abstract The crystal structures of diphenyl(diphenylsulfimido)(nitrido)sulfur(VI) (Ph~2~S=N–(Ph~2~)S≡N) (**1**) and diphenyl(diphenylsulfodiimido)(nitrido)sulfur(VI) (Ph~2~(HN=)S=N–(Ph~2~)S≡N) (**2**) were determined by X‐ray crystallographic analysis. The former has a bent S–N–S unit with bridg