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Formation of [S(CN)2]n in the solid phase reaction of ICN and KSCN

✍ Scribed by Z. Tóth; M.T. Beck

Book ID: 108328274
Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 162 KB
Volume: 141
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)86360-4

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The CIHzNz isomers CH,\_N-CN and HN=CH-CN have been selectively generated, the former by flash vacuum pyrolysis of trimethylenetetrazole and SH, lOH-dihydroditetrazolo [ 15-a: 1',5'-d] pyrazine; the latter from azidoacetonitrile and from the lithium and sodium salts of the tosylhydrazone of I-cyanof