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Formation of Ruthenium Nitrosyl Complexes: Reactions of Ru(bpy)(CO) 2 Cl 2 and Its Methyl-Substituted Analogues Ru(4,4‘-dmbpy)(CO) 2 Cl 2 and Ru(6,6‘-dmbpy)(CO) 2 Cl 2 in Oxidizing Acidic Solutions

✍ Scribed by Homanen, Pertti; Haukka, Matti; Ahlgrén, Markku; Pakkanen, Tapani A.

Book ID
125486302
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
40 KB
Volume
36
Category
Article
ISSN
0020-1669

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📜 SIMILAR VOLUMES

Selective Formation of cis(X)- and trans
Selective Formation of cis(X)- and trans(X)-Ru(dmbpy)(CO)2X2 Complexes (X = Cl, Br, I, SCN) from Monomeric and Dimeric Ru–mono(dmbpy) Carbonyl Complexes (Dmbpy = 4,4′-Dimethyl-2,2′-bipyridine)
✍ Pertti Homanen; Matti Haukka; Saija Luukkanen; Markku Ahlgrén; Tapani A. Pakkanen 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 161 KB 👁 1 views

Aqueous hydrogen halides HX (X = Cl, Br, I) are shown to containing derivatives, but the only stable isomer containing iodine was trans(I)-Ru(dmbpy)(CO) 2 I 2 . The failure to obtain be excellent halogen sources for the synthesis of a series of halogen-containing ruthenium mono(2,2Ј-bipyridine) car-