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Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol

✍ Scribed by G. G. Lazarev; V. L. Kuskov; Ya. S. Lebedev


Book ID
112447480
Publisher
Springer
Year
1991
Tongue
English
Weight
303 KB
Volume
40
Category
Article
ISSN
1573-9171

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The formation of radical pairs with a dipole-dipole splitting constant D= 12.2 t 0.2 mT upon photolysis of single crystals of 2,6-di-tert-butyl-4-methylphenol doped with IO-' M 2,6-di-tert-butyl-1-imino-pquinone was studied by EPR spectroscopy in the temperature range between 77 and 140 K. The mecha

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The role of dopant geometry in the photo
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Radical pairs are formed by photolysis of single crystals of 2,6-di-tert-butyl-4-methylphenol (ionol) (1) or 2,6-di-tert-butylphenol (2 ), doped by several different molecules, and investigated by the EPR method. A possible two-hydrogen-atom transfer is discussed as the photochemical act.