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Formation of radical pairs by photochemical reduction of sterically hindered quinones with phenols in frozen solutions

โœ Scribed by A. I. Aleksandrov; N. N. Bubnov; G. G. Lazarev; Ya. S. Lebedev; A. I. Prokof'ev; M. V. Serdobov


Book ID
112481521
Publisher
Springer
Year
1976
Tongue
English
Weight
445 KB
Volume
25
Category
Article
ISSN
1573-9171

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Stable radical pairs under the photolysi
โœ G.G. Lazarev; V.L. Kuskov; Ya.S. Lebedev ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 437 KB

Intermediate radical products, which are formed when monocrystals of sterically hindered phenols containing lo-' M Z&k&tbutyl quinone diazide are photolysed, have been studied employing EPR. We have identified the formation of carbenes and several types of radical pairs It is found that, with a rise