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Formation of Phenylcarbenes by Photolysis of Phenyloxiranes

✍ Scribed by Dr. H. Kristinsson; Prof. Dr. G. W. Griffin

Book ID
101549455
Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
117 KB
Volume
4
Category
Article
ISSN
0044-8249

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Laser flash photolysis (LFP, XeCl, 308 nm, 20 ns) of phenyldiazomethane (PDM), o-tolydiazomethane (TDM) and mesitydiazomethane (MDM) produces phenylcarbene (PC), o-tolycarbene (TC) and mesitylcarbene (MSC), respectively. Transient spectra of PC and TC could not be detected in pentane at ambient temp