๐”– Bobbio Scriptorium
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Formation of partially trimethylsilylated derivatives of carbohydrates. The trimethylsilyl tris-o-trimethylsilyl-d-glucopyranosides and tetrakis-o-trimethylsilyl-d-glucose

โœ Scribed by Sung Man Kim; Ronald Bentley; C.C. Sweeley


Book ID
108307810
Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
995 KB
Volume
5
Category
Article
ISSN
0008-6215

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An improved preparation of 2,3,5-tri-O-a
โœ Anton ล timac; Joลพe Kobe ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 514 KB

An improved synthesis ' of 2,3,5-tri-O-benzoyl-/3-o-ribofuranosyl azide (3) involves the reaction of trimethylsilyl azide in the presence of a Lewis acid with l-0-acetyl-2,3J-tri-O-benzoyl-@-o-ribofuranose 2-4 (1) rather than the action of sodium azide upon the corresponding halide 5. Titanium tetra