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Formation of optically active 3-methylphthalide by a displacement with methylcadmium chloride

✍ Scribed by Paul R. Jones; Carl J. Jarboe

Book ID: 104239356
Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 145 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)88029-1

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✦ Synopsis

We wish to report the first example of formation of an optically active product by displacement at a saturated carbon atom effected by an organocadmium reagent. The work was undertaken as part of a continuing effort to gain an understanding of the unusual reaction (1) (Equation 1). in which a phthalide (2) with a 3-substituent undergoes

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