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Formation of (MgCl2)x Polynuclear Species During Preparation of Active MgCl2 Supported Ziegler–Natta Catalysts from Solid Solvates with Lewis Bases

✍ Scribed by Auriemma, Finizia; Rosa, Claudio De


Book ID
111965739
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
136 KB
Volume
19
Category
Article
ISSN
0897-4756

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The initial polymerization stage of propene with a MgClz-supported Ziegler catalyst after the pre-treatment with a Lewis base was examined as a study of the stereospecificity of the active sites precursors. A drastic depressing effect on the catalyst activity occurs, accompanied by an increase in st