Formation of methyl radicals during the oxidative addition of iodomethane to a single-crystal copper surface
β Scribed by Lin, Jong Liang; Bent, Brian E.
- Book ID
- 126008963
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 599 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The equilibrium surface segregation of Ag to the low-index surfaces of Cu single crystals is presented. It is found that the close-packed surface of the (111) orientation allows a high interaction parameter resulting in a discontinuous transition in the surface concentration against temperature, as
The participation of a 1,3-hydrogen shift in initially formed secondary alkoxyethyl radicals R 1 R 2 CH-O-CH -CH 3 during their free-radical chain additions to methyl 2,3,3-trifluoroacrylate has been confirmed using a deuterium marked additive. Indirect evidence has been obtained for a partial 1,3-h