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Formation of Ions from Compounds with Conjugated Double Bonds: Hydrocarbon Salts

✍ Scribed by WEISS, JOSEPH

Book ID: 109536113
Publisher: Nature Publishing Group
Year: 1941
Tongue: English
Weight: 102 KB
Volume: 147
Category: Article
ISSN: 0028-0836
DOI: 10.1038/147512a0

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## Abstract The reaction of a highly crowded dihydrostibine [2,4,6‐tris[bis(trimethylsilyl)methyl]phenyl‐SbH~2~ (TbtSbH~2~) (**1**)] with elemental sulfur in the presence of nitrile oxides resulted in the formation of [2 + 3] cycloaddition reaction products of a thioxostibine [TbtSb=S (**6**)] and