Formation of Honeycomb Structures and Superhydrophobic Surfaces by Casting a Block Copolymer from Selective Solvent Mixtures

✍ Scribed by Pao-Hsiang Tung; Shiao-Wei Kuo; Kwang-Un Jeong; Stephen Z. D. Cheng; Chih-Feng Huang; Feng-Chih Chang

• Publisher: John Wiley and Sons
• Year: 2007
• Tongue: English
• Weight: 356 KB
• Volume: 28
• Category: Article
• ISSN: 1022-1336
• DOI: 10.1002/marc.200600612

✦ Synopsis

Abstract

Poly(vinyl phenol)‐block‐polystyrene (PVPh‐b‐PS) diblock copolymers are synthesized by sequential anionic polymerization with sec‐butyl lithium as the initiator. The PVPh‐b‐PS diblock copolymer is cast (on a substrate) from several solvent mixtures that contain tetrahydrofuran/toluene ratios of 1:0.1, 1:1, and 1:2. After solvent evaporation the resulting films are characterized by SEM, TEM, and contact angle measurements. A honeycomb structure is fabricated from the vesicle structure at relatively low toluene contents. On the contrary, at relatively higher toluene contents, a micelle structure with porous microspheres is formed, which possesses higher surface roughness and results in film surface superhydrophobicity. The simple method described here that uses common/selective mixed solvents may be easily extended to prepare honeycomb structures and superhydrophobic surfaces simultaneously from a wide variety of block copolymers by carefully controlling the weight composition of the block copolymer and the selective solvent content.

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