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Formation of Helical J -Aggregate of Chiral Thioether-Derivatized Phthalocyanine Bound by Palladium(II) at the Toluene/Water Interface

✍ Scribed by Adachi, Kenta; Chayama, Kenji; Watarai, Hitoshi


Book ID
117998521
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
615 KB
Volume
22
Category
Article
ISSN
0743-7463

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Control of optically active structure of
✍ Kenta Adachi; Kenji Chayama; Hitoshi Watarai 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 571 KB

## Abstract The Pd(II)‐2,2′‐bis(diphenylphosphino)‐1,1′‐binaphthyl (BINAP)‐mediated chiral assembly of thioether‐derivatised phthalocyanatomagnesium(II) compounds (MgPc(SR)~8~, SR is benzylthio (SBz) or benzhydrylthio (Bh)) was formed in toluene and at the toluene/water interface, and investigated