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Formation of H2O2 by adiabatic expansion of H2-O2 gas mixtures

✍ Scribed by John W Hastie

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 341 KB
Volume: 17
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)87052-0

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✦ Synopsis

studies of adiabatic espansions of Hz-0:~ and Hz-Oz-NZ gas mixtures have revealed the formation of the species Hz.02 at concentrations of the order o?' 10 +-lo4 mole fraction. This species is believed to be a relatively weakly bound isomer which is less stabIe than t1202, the cOrnman form of hydrogen peroxide. A mechanism which is more consistent with the data is: Hz + H2 f 02 + Hz.02 + Hz,

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