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Formation of gold(I) halide and thiocyanate complexes in pyridine and acetonitrile and the structures of gold(I) solvates in these solvents. A thermodynamic and EXAFS spectroscopic study

✍ Scribed by Ahrland, Sten; Nilsson, Karin; Persson, Ingmar; Yuchi, Akio; Penner-Hahn, James E.


Book ID
127092490
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
694 KB
Volume
28
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES


Ionic solvationβ€”Part 7. Cation solvation
✍ Andrzej Lewandowski πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 486 KB

The stability constants of silver(I) complexes with cryptand 222 have been determined by potentiometric titration in dimethylsulphoxide (DMSO) + acetonitrile (AN) mixtures. It has been shown that the experimental data can be correlated via the following equation: where KAB and KA are the cryptate s