A method is described for the production of large cluster ions by direct laser vaporization in a low-pressure FTMS. Production of high-mass carbon cluster ions (C,' ; 40 < n < 180) and bismuth-antimony (Bi,Sb,? ) cluster ions containing up to five metal atoms are reported. The observed distributions
Formation of gold cluster cations by direct laser vaporization
β Scribed by Mehdi Moini; John R. Eyler
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 292 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
1 to 6 have been produced by direct laser vaporization of gold metal in a Fourier transform ion cyclotron resonance mass spectrometer. Wavelength studies at t= 532, 355, and 266 nm show similar results. However, the intensities and intensity ratios of the cluster ions strongly depended on laser power at the two longer wavelengths. Ionization energies of Au + , Au: , and Au: have also been estimated.
π SIMILAR VOLUMES
Two reaction channels have been found when light hydrocarbon gases are introduced into the carrier gas of a plasma reactor coupled with a laser vaporization source employing a metal rod assembly. These involve dehydrogenation to produce pure carbon clusters, and formation of metal-carbon bonds to pr
Hydrogenated carbon cluster ions (C,Hz ) were produced by laser ablation of aromatic compounds and studied by a timeofflight mass spectrometer. A series of clusters with about 8 hydrogen atoms for the middle-mass region (30 x n-z 60) and a new set of clusters with specific number of hydrogen atoms f