Formation of gas-phase negative ions in Fe(CO)5 and Ni(CO)4
✍ Scribed by R.N. Compton; J.A.D. Stockdale
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 534 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0020-7381
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When starting with racemates, OY,,,,, = -l)i([j" + I ) , while for a sample ofcomposition (tl, I ) OY,,, = j([jd + 1) -2(/k/41'2)!tl(/1 -1). The optical yield can be related to the thermodynamic chirdl recognition. AAG = -RT1nl.i. as /j = [(I + OY)/(l -OY]' when d = l = I = 0.5 (0 s OY < 1 ). [12]
## Abstract __Fourier__‐transform ion‐cyclotron‐resonance mass spectrometry is used to investigate the reactions of mass‐selected homo‐ and heteronuclear clusters MM′^+^ (M, M′=Fe, Co, Ni) with linear alkanenitriles. The reactions with pentanenitrile are examined in detail by means of deuterium‐lab