Formation of free radicals during machining and fracture of polymers
โ Scribed by Backman, D. K. ;Devries, K. L.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1969
- Tongue
- English
- Weight
- 779 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0449-296X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
thyldecatriene. With divinylbenzene, both vinyl groups can take part in the reaction, and the products include FH3 FH3 CH=CH-CHZ-C=CH-CH~-CH~-C=CH-CH~ -0 (13) didecatrienylbenzene and vinyldecatrienylbenzene. a-Substituted styrenes such as cr-methylstyrene are much less reactive than styrene itself
It has been found that free radicals produced in cross-linked rubbers subjected to high stresses can be detected in E.S.R. either as alkylperoxy radicals or by reacting with a phenol which can give rise to a stable free radical (galvinoxyl). This reaction occurs only during the first 1ยฝ hr of stress