Formation of Diol Divinyl Diethers in the Synthesis of 1,2-Epoxy-3-(vinyloxyalkoxy)propanes
โ Scribed by T. V. Raskulova; L. I. Volkova; Yu. S. Danilevich; B. A. Shainyan; A. K. Khaliullin
- Book ID
- 110390283
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2002
- Tongue
- English
- Weight
- 27 KB
- Volume
- 38
- Category
- Article
- ISSN
- 1070-4280
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract A convenient procedure has been developed for the synthesis of ^14^Cโ3โchloropropanโ1, 2โdiol (ฮฑโchlorohydrin, **I**) from ^14^Cโglycerol which can also be applied to the preparation of ^14^Cโ3โbromopropanโ1, 2โdiol (ฮฑโbromohydrin, **III**). These two compounds can be converted, respect
were obtained in optically pure form by chiral Staudinger reaction. The cis-al~-ratio could be influenced by the protective groups of the diol moiety. Removal of the chiral auxiliarity could be accomplished by direct oxidation, or by previous double bond formation, thus the 2-amino-l-phenyl-propan-l