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Formation of Cyclopropanone during Cytochrome P450-Catalyzed N-Dealkylation of a Cyclopropylamine

โœ Scribed by Shaffer, Christopher L.; Harriman, Shawn; Koen, Yakov M.; Hanzlik, Robert P.

Book ID
121295846
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
84 KB
Volume
124
Category
Article
ISSN
0002-7863

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## Abstract Most peroxidases use histidine as an axial ligand for heme, while chloroperoxidase (CPO) uses a thiolate, which is similar to the ligand employed by cytochrome P~450~ (P~450~). Several studies have also shown that, unlike other peroxidases, CPO is capable of carrying out monooxygenation