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Formation of cis,cis-1,4-dicyano-1,3-butadienes by thermal decomposition of 1,2-diazidobenzenes

✍ Scribed by Hall, John Herbert.; Patterson, Eric.


Book ID
121348515
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
707 KB
Volume
89
Category
Article
ISSN
0002-7863

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Thermal dimerization of 1,3-butadiene: K
✍ G. Huybrechts; L. Luyckx; Th. Vandenboom; B. Van Mele πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 478 KB

## Abstract The thermal reaction of 1,3‐butadiene (BD) has been studied between 464 and 557Β°K at pressures between 49 and 450 torr. The products are 4‐vinylcyclohexene (VCH) and __cis__, __cis__‐cycloocta‐1,5‐diene (COD), and their formations are second order. The rate constant (in 1/mol Β· sec) for