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Formation of Chlorinated Aromatics by Reactions of Cl • , Cl 2 , and HCl with Benzene in the Cool-Down Zone of a Combustor

✍ Scribed by Procaccini, Carlo; Bozzelli, Joseph W.; Longwell, John P.; Sarofim, Adel F.; Smith, Kenneth A.


Book ID
126120253
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
149 KB
Volume
37
Category
Article
ISSN
0013-936X

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The structure, stability, and reactivity of the [C,H 3 ,Cl 2 ] ions from the reaction of Cl 3 with CH 4 were studied by structurally diagnostic mass spectrometric techniques and by computational methods. The ionic products were characterized as protonated dichloromethane [ClH 2 CÀClH] (1), the more