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Formation of· CH2CH2CO + and C2H6+· in the metastable decompositions of ionized ethyl formate

✍ Scribed by Charles E. Hudson; David J. McAdoo

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
489 KB
Volume
27
Category
Article
ISSN
1076-5174

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✦ Synopsis

The products of the metastable decompositions of ionized ethyl formate (a) are characterized. The loss of water from a produces 'CH,CH,CO+, a rarely reported product. Loss of H appears to produce CH,=CHC(OH)i. The third decomposition is an unusual formation of C,Hl'. This work demonstrates that a previous supposition that isomerization to different intermediates is involved in the losses of ethene and of water from a is correct.

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