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Formation of Cationic Half-Sandwich Osmium−Vinylidene Complexes from [Os(η 5 -C 5 H 5 )(P i Pr 3 ) 2 ] + and Terminal Alkynes

✍ Scribed by Baya, Miguel; Crochet, Pascale; Esteruelas, Miguel A.; López, Ana M.; Modrego, Javier; Oñate, Enrique

Book ID
126316865
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
95 KB
Volume
20
Category
Article
ISSN
0276-7333

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Synthesis and Characterization of Hydride−Alkynyl, Allenylidene, Carbyne, and Functionalized-Alkynyl Complexes Containing the [Os( η 5 -C 5 H 5 )(P i Pr 3 ) 2 ] + Fragment: The Complex [Os( η 5 -C 5 H 5 )(CCCPh 2 )(P i Pr 3 ) 2 ]PF 6 , a New Type of Allenylidene Derivative from the Reactivity Point of View
✍ Baya, Miguel; Crochet, Pascale; Esteruelas, Miguel A.; Gutiérrez-Puebla, Enrique 📂 Article 📅 2000 🏛 American Chemical Society 🌐 English ⚖ 300 KB