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Formation of carboxylato copper oxygen complexes in the reaction of metallic copper with 1,2-dicarbonyls and dioxygen

✍ Scribed by Gábor Speier; Zoltán Tyeklár

Publisher
Springer
Year
1992
Tongue
English
Weight
363 KB
Volume
17
Category
Article
ISSN
0340-4285

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✍ Sukanta Mandal; Anindita De; Rabindranath Mukherjee 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 375 KB 👁 1 views

## Abstract Reaction of a Cu^I^ complex of a hybrid tridentate ligand, encompassing [2‐(pyridin‐2‐yl)ethyl]amine and dimethyl‐substituted ethylalkylamine with dioxygen, generates in acetone at −80° putative bis(__μ__‐oxo)dicopper(III) intermediate. Structural characterization of a PPh~3~‐adduct of