✦ LIBER ✦
Formation of carbamates by reaction between ester carbanions and isocyanates: General regularities and scope
✍ Scribed by Yuri G. Gololobov; Yuri A. Borisov; Nikolii Slepchenkov; Sergey Barabanov; Pavel V. Petrovskii; Julija V. Nelyubina
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 140 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1042-7163
- DOI
- 10.1002/hc.20585
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✦ Synopsis
Abstract
General regularities and scope of reactions carbanions with the ester group at carbanionic center and arylisocyanates resulting formation of carbamates by C → N migrations of ester groups have been described. The use of tosylisocyanates terminated reactions at the first stage with formation of corresponding tosylacylamides. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:119–125, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20585