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Formation of bilayer structure through face-to-face π–π interactions

✍ Scribed by Lei Jia; Ning Tang; Jagadese J. Vittal


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
454 KB
Volume
920
Category
Article
ISSN
0022-2860

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✍ Ichiro Hisaki; Yuu Sakamoto; Hajime Shigemitsu; Norimitsu Tohnai; Mikiji Miyata; 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 801 KB

## Abstract To develop a novel π‐conjugated molecule‐based supramolecular assembly, we designed and synthesized trisdehydrotribenzo[12]annulene ([12]DBA) derivative **2** with three carboxyl groups at the periphery. Recrystallization of **2** from DMSO gave a crystal of the solvate **2⋅**3 DMSO. Cr