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Formation of Aryl−Nitrogen, Aryl−Oxygen, and Aryl−Carbon Bonds Using Well-Defined Copper(I)-Based Catalysts

✍ Scribed by Gujadhur, Rattan K.; Bates, Craig G.; Venkataraman, D.

Book ID
111692305
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
90 KB
Volume
3
Category
Article
ISSN
1523-7060

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Formation of arylnitrogen bonds using a
Formation of arylnitrogen bonds using a soluble copper(I) catalyst
✍ Rattan Gujadhur; D Venkataraman; Jeremy T Kintigh 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 57 KB

We report a synthetic protocol for the synthesis of functionalized diaryl-and triarylamines under mild conditions, using a soluble, air-stable copper(I) complex, Cu(PPh 3 ) 3 Br, as the catalyst and cesium carbonate as the base. Using this protocol, we were able to synthesize a tri-ortho-ester funct