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Formation of ArPdXL(amine) Complexes by Substitution of One Phosphane Ligand by an Amine in trans-ArPdX(PPh3)2 Complexes

✍ Scribed by Anny Jutand; Serge Négri; Anna Principaud

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
104 KB
Volume
2005
Category
Article
ISSN
1434-1948

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Enolate-Phosphane Ligands Providing a To
Enolate-Phosphane Ligands Providing a Tool for the Selective Substitution of Triphenylphosphane by Carbon Monoxide or Trimethylphosphane in Complex {Ru(Cp)[η2-P,O-Ph2PCH2C(tBu)=O](PPh3)}[PF6], and Subsequent Reactivity Towards Terminal Alkynes
✍ Bernard Demerseman; Loïc Toupet 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 203 KB 👁 2 views

## Abstract The deprotonation under basic conditions of the keto‐phosphane ligand in complexes {Ru(Cp)[η^1^‐__P__‐Ph~2~PCH~2~C(=O)__t__Bu](PPh~3~)(L)}[PF~6~] (L = CO or PMe~3~) that arise from the addition of L to {Ru(Cp)[η^2^‐__P__,__O__‐Ph~2~PCH~2~C(__t__Bu)=O](PPh~3~)}[PF~6~] generates {Ru^+^(Cp