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Formation of Anionic Trifunctionalized Metallalactones by Nucleophilic Addition at the β-Carbonyl of a Pyruvoyl Ligand

✍ Scribed by Cabon, P.; Rumin, R.; Salaün, J. Y.; Triki, S.; des Abbayes, H.


Book ID
126440583
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
197 KB
Volume
24
Category
Article
ISSN
0276-7333

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Formation of a reasonably stabilized tri
✍ Tatsuya Shono; Manabu Ishifune; Osamu Ishige; Hiroshi Uyama; Shigenori Kashimura 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 260 KB

A reasonably stabilized trichloromethyl anion (TCMA) was formed by the reaction of chloroform with an electrogenerated base prepared by the electroreduction of Zpyrrolidone, and the addition of this TCIvIA to a$unsaturated esters gave the corresponding B-trichloromethyl esters in good yields.