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Formation of (alkoxymethylene)dimethylimmonium halides in the reactions of triphenylphosphine dihalides with alcohols in dimethylformamide

✍ Scribed by Johnson, Roy A.; Herr, Milton E.

Book ID
121502892
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
386 KB
Volume
37
Category
Article
ISSN
0022-3263

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## Abstract The reactivity of the lithium halides in 83.3% pyridine‐dimethylformamide changes from Cl^βˆ’^ > Br^βˆ’^ > I^βˆ’^ to Br^βˆ’^ > I^βˆ’^ to Br^βˆ’^ > I^βˆ’^ > Cl^βˆ’^ with increasing concentration of the salt from 0 to 0.35 M. This behaviour is explained by ion pairing which reduces the concentration of r