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Formation of a Stable, Lattice-Framework Disilene: A Strategy for the Construction of Bulky Substituents

โœ Scribed by Shigeki Matsumoto; Shinobu Tsutsui; Eunsang Kwon; Kenkichi Sakamoto


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
166 KB
Volume
43
Category
Article
ISSN
0044-8249

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Formation of a Stable, Lattice-Framework
โœ Shigeki Matsumoto; Shinobu Tsutsui; Eunsang Kwon; Kenkichi Sakamoto ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 166 KB

Recently, the reversible tetramerization of a diaminosilylene was reported; [12] 1 is a formal tetramer of tri(tertbutyl)cyclopropenylsilylyne. Although the formation pathway of 1 remains uncertain, multistep reactions include the reduction of the silicon-bromine bonds, isomerization, [6, 7, 13] and