Formation of a Spiral-Shaped Inorganic−Organic Hybrid Chain, [Cu II (2,2‘-bipy)(H 2 O) 2 Al(OH) 6 Mo 6 O 18 ] n n - : Influence of Intra- and Interchain Supramolecular Interactions

Inorganic-Organic Hybrid Materials: Synt

Inorganic-Organic Hybrid Materials: Synthesis and Structure of a Reduced Ferrous Molybdophosphate, [(C12H8N2)3FeII]2[Fe11MOV12(H2PO4)6(PO4)2(OH)6O24], in the Presence of Fe(II)(1,10-Phenanthroline)3 Complex

✍ Yun-Shan Zhou; Li-Juan Zhang; Xiao-Zeng You; Srinivasan Natarajan 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 430 KB

The structure of 1 is built up from FeMo 12 (H 2 PO 4 ) 6 (PO 4 ) 2 (OH) 6 O 4؊ 24 cluster anions connected to each other via hydrogen bonds. The arrangement of clusters is such that each cluster is surrounded by six equivalent anions resulting in three-dimensional cavities. The charge balancing cat