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Formation of a benzopyrylium ion and a quinoline from benzofuran

✍ Scribed by Sonnenschein, Helmut ;Schmitz, Ernst ;Pritzkow, Wolfgang

Book ID: 102367094
Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 274 KB
Volume: 1990
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199019900150

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✦ Synopsis

Abstract

Chlorophenylcarbene reacts with benzofuran to give the cyclopropane derivative 3, which undergoes thermal opening of the three‐membered ring to give the benzopyrylium cation 5. With aniline, 3 forms the quinoline 11 containing two C atoms of the starting compound 1 in positions 2 and 4.

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