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Formation of 3-Methyl-1-adamantyl Trifluoromethanesulfonate in the Reaction of 3,7-Dimethylenebicyclo[3.3.1]nonane with Trifluoromethanesulfonic Acid. Dissociation and Carbocationic Rearrangements

โœ Scribed by A. M. Genaev; V. A. Sokolenko; G. E. Sal'nikov; V. I. Mamatyuk; V. G. Shubin


Book ID
110400601
Publisher
SP MAIK Nauka/Interperiodica
Year
2002
Tongue
English
Weight
55 KB
Volume
38
Category
Article
ISSN
1070-4280

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The carbonylat-ion of the l-adama~tyl cation with carbon monoxide In carbon tetrachlorfde at atmosoher$c oressure in the oresence of tr6f3uacondittcns.. Among various l-adakantyl cation pre&rsors teste& l~ad~~t~~ trjfluor~thanesulfo~ate (tr\*ftatef and ~tbanesul~onate (mesylate) have gfven the best,