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Formation of 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2-(m-chlorobenzoyloxy)-3-(phenylseleno)propan-1-ol from a reaction of allyl phenyl selenide withm-chloroperoxybenzoic acid

✍ Scribed by Takanori Hirose; Nobuhiro Morita; Mitsuhiro Asakura; Keisuke Kitahara; Shinji Toyota; Michinori O¯ki

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
229 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

Oxidation of allyl phenyl selenide with m-chloroperoxybenzoic acid unexpectedly afforded two compounds, the structures of which were determined as 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2-(m-chlorobenzoyloxy)-3-(phenyl';eleno)propan-l-ol. Structure determination of the products is described and the possible mechanisms are discussed.

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