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Formation of 2,4,4-Trimethylthiete by Photodecarbonylation of 3,3,5-Trimethyl-2(3H)-thiophenone

✍ Scribed by Dipl.-Chem. Heiko Hinrichs; Prof. Dr. Paul Margaretha


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
265 KB
Volume
28
Category
Article
ISSN
0044-8249

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Two new 1,2,3,5-dithiadiazoles, [4-(4Ј-C 5 H 4 N)CN 2 S 2 ] (L 1 ) and [4-(3Ј-C 5 H 4 N)CN 2 S 2 ] (L 2 ), with different pyridyl groups at the 4-position were prepared. As Lewis bases, the dithiadiazoles reacted with Lewis acids via their pyridyl groups to form acid-base adducts with retention of t