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Formation of 2-Substituted Iodobenzenes from Iodobenzene via Benzyne and Ate Complex Intermediates

✍ Scribed by Tripathy, Sasmita; LeBlanc, Richard; Durst, Tony


Book ID
121418733
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
123 KB
Volume
1
Category
Article
ISSN
1523-7060

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Selective coupling of olefins and terminal acetylenes is nation sequence. [Ru(tp)(COD)Cl] and [Ru(tp){Ξ· 3 -(P,C,C)-Ph 2 PCH=CHC(Ph)=CH 2 }Cl] were the starting materials shown to be effected in the coordination sphere of Ru II by the successive intermediacy of vinylidene and which were treated with