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Formation of 2-keto-α-cyperone by oxidation and rearrangement of 3-hydroxysolavetivone

✍ Scribed by Robert C. Anderson; Ian Bryson; Ian Bryson; James S. Roberts; Sharon E. Watson

Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 106 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)88153-8

No coin nor oath required. For personal study only.

✦ Synopsis

Mild oxidation of the tobacco sesquiterpenoid, 3_hydroxysolavetivone,

gives the corresponding cu-diketone which undergoes a facile thermal rearrangement to Z-keto-a-cyperone.

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