𝔖 Bobbio Scriptorium
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Formation of 2-keto-α-cyperone by oxidation and rearrangement of 3-hydroxysolavetivone

✍ Scribed by Robert C. Anderson; Ian Bryson; Ian Bryson; James S. Roberts; Sharon E. Watson


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
106 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis


Mild oxidation of the tobacco sesquiterpenoid, 3_hydroxysolavetivone,

gives the corresponding cu-diketone which undergoes a facile thermal rearrangement to Z-keto-a-cyperone.


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Rearrangement of 2,3-disubstituted benzo
✍ Waldemar Adam; Markus Sauter 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 429 KB

## Benz&ran epoxidcs. prepared by dimethyldioxirane (DMD) ox&tion of the cowesponding 23-disubstituted benzo$uronr, @rd on 1,2 m&ration tk respectiw ben@ronones 4a,&f, except 3-tert-butyl-2-methylbemojiuon epoti (2~). which persists even at room tempemtw e: however, on DMD oxidabn of 2-methylberuq