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Formation of 2-indanone and benzocyclobutene from the pyrolysis of phenyl propargyl ether

โœ Scribed by Trahanovsky, Walter S.; Mullen, Patrick W.


Book ID
127024099
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
349 KB
Volume
94
Category
Article
ISSN
0002-7863

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A few years ago we reported that the flash vacuum pyrolysis (F'VP) of phenyl propargyl ether (L) gives substantial yields of 2-indanone (2, 26%) and 1,2-dihydrobenzocyclobutene (3, 31$).l The mechanism shown inthe Scheme was proposed to account for the formation of 2. No mechanism 2 was proposed but

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## Abstract A value of the enthalpy of formation of the phenoxy radical in the gas phase, ฮ”__H__ยฐ~,298K~ (ฯ•Oยท, g) = 11.4 ยฑ 2.0 kcal/mol, has been obtained from the kinetic study of the unimolecular decompositions of phenyl ethyl ether, phenyl allyl ether, and benzyl methyl etherTrivial names for et