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Formation of 1O2 in the Reversible Autoxidation of Enolates Derived from Carboxylic Acids

✍ Scribed by Prof. Dr. Waldemar Adam; Dr. Omar Cueto; Hector Rebollo


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
114 KB
Volume
21
Category
Article
ISSN
0044-8249

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The kinetics of the isotope exchange reactions of RCH(COOH) 2 (R"H, D, Me, Et, Bu, and Ph) in D 2 O solution were studied by using 1 H NMR spectroscopy. It was observed that the rate of isotope exchange reaction was inhibited by the presence of 1 M of DNO 3 , DCl, DBr or D 2 SO 4 and catalyzed by th