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Formation of 1-deoxy-d-erythro-2,3-hexodiulose from Amadori compounds

✍ Scribed by Jakob Beck; Franz Ledl; Theodor Severin


Book ID
102994716
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
261 KB
Volume
177
Category
Article
ISSN
0008-6215

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Formation of 1,5-lactones from 3-deoxy-d
✍ Daniel Charon; France-Isabelle Auzanneau; Claude MΓ©rienne; Ladislas SzabΓ³ πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 271 KB

Acylation of ammonium 3-deoxy-n-D-manno-Z-octulopyranosonate (la) leads to the formation of peracetylated 3-deoxy-a-D-manno-2-octulopyranosono-1,5-lactones (3a,b). The proposed structures were confirmed by independent syntheses. The 1,7-lactone was not formed even when only OH-7 was available for la